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This equilibrium is manifested when the salt is dissolved and when the solid is heated. Characteristic of other bifluorides, it reacts with acids to give HF. Illustrative is its reaction with bisulfate to form sodium sulfate and hydrogen fluoride. Strong bases deprotonate bifluoride. For example, calcium hydroxide gives calcium fluoride. [5]
Soluble fluoride salts, of which sodium fluoride is the most common, are toxic, and have resulted in both accidental and self-inflicted deaths from acute poisoning. [4] The lethal dose for most adult humans is estimated at 5 to 10 g (which is equivalent to 32 to 64 mg elemental fluoride per kg body weight).
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Tetra-n-butylammonium fluoride, commonly abbreviated to TBAF and n-Bu 4 NF, is a quaternary ammonium salt with the chemical formula (CH 3 CH 2 CH 2 CH 2) 4 N + F −. It is commercially available as the white solid trihydrate and as a solution in tetrahydrofuran. TBAF is used as a source of fluoride ion in organic solvents. [1]
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