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Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al 2 O 3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and ...
The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, [Co(NH 3) 6] 3+, which is not octahedral in the mathematical sense due to the orientation of the N−H bonds, is referred to as octahedral. [2]
Aluminium(I) oxide (Al 2 O) Aluminium(II) oxide ( AlO ) (aluminium monoxide) Aluminium(III) oxide (aluminium oxide), ( Al 2 O 3 ), the most common form of aluminium oxide, occurring on the surface of aluminium and also in crystalline form as corundum , sapphire , and ruby .
Aluminates are often formulated as a combination of basic oxide and aluminium oxide, for example the formula of anhydrous sodium aluminate NaAlO 2 would be shown as Na 2 O·Al 2 O 3. A number of aluminate oxyanions are known: The simplest is the approximately tetrahedral AlO 5− 4 found in the compound Na 5 AlO 4, [2] framework AlO −
In clays, the tetrahedral sheets are always bonded to octahedral sheets formed from small cations, such as aluminum or magnesium, and coordinated by six oxygen atoms. The unshared vertex from the tetrahedral sheet also forms part of one side of the octahedral sheet, but an additional oxygen atom is located above the gap in the tetrahedral sheet ...
Corundum is a crystalline form of aluminium oxide (Al 2 O 3) typically containing traces of iron, titanium, vanadium, and chromium. [3] [4] It is a rock-forming mineral.It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. [7]
[Al 6 (t Bu) 6] •-cluster, as synthesized by Linti et al. [6] This is the first octahedral aluminium cluster synthesized. This method of cluster formation created the only known incidence of an octahedral aluminium cluster, [Al 6 (tBu) 6] −, which was formed by reaction between AlCl and t BuLi. [6]
For example, in the rock salt ionic structure each sodium atom has six near neighbour chloride ions in an octahedral geometry and each chloride has similarly six near neighbour sodium ions in an octahedral geometry. In metals with the body centred cubic (bcc) structure each atom has eight nearest neighbours in a cubic geometry.