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The circumstances under which a compound will have ionic or covalent character can typically be understood using Fajans' rules, which use only charges and the sizes of each ion. According to these rules, compounds with the most ionic character will have large positive ions with a low charge, bonded to a small negative ion with a high charge. [25]
Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, [1] and is the primary interaction occurring in ionic compounds.
The resulting compound is called an ionic compound, and is said to be held together by ionic bonding. In ionic compounds there arise characteristic distances between ion neighbours from which the spatial extension and the ionic radius of individual ions may be derived. The most common type of ionic bonding is seen in compounds of metals and ...
Ionic compounds can also be produced from their constituent ions by evaporation of their solvent, precipitation, freezing, a solid-state reaction, or the electron transfer reaction of reactive metals with reactive non-metals, such as halogen gases. Ionic compounds typically have high melting and boiling points, and are hard and brittle.
This is analogous to related compounds such as hydrogen peroxide, hydrogen sulfide, and deuterium oxide (heavy water). Using chemical nomenclature for type I ionic binary compounds, water would take the name hydrogen monoxide, [105] but this is not among the names published by the International Union of Pure and Applied Chemistry (IUPAC). [102]
Ionic bonding, which forms ionic solids; Metallic bonding, which forms metallic solids; Weak inter molecular bonding, which forms molecular solids (sometimes anomalously called "covalent solids") Typical members of these classes have distinctive electron distributions, [2] thermodynamic, electronic, and mechanical properties. In particular, the ...
Inorganic compounds exhibit a range of bonding properties. Some are ionic compounds, consisting of very simple cations and anions joined by ionic bonding.Examples of salts (which are ionic compounds) are magnesium chloride MgCl 2, which consists of magnesium cations Mg 2+ and chloride anions Cl −; or sodium hydroxide NaOH, which consists of sodium cations Na + and hydroxide anions OH −.
The characteristics of the bond formed can be predicted by the properties of constituent atoms, namely electronegativity. They differ in the magnitude of their bond enthalpies , a measure of bond strength, and thus affect the physical and chemical properties of compounds in different ways. % of ionic character is directly proportional ...