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Sodium zincate refers to anionic zinc oxides or hydroxides, depending on conditions. In the applications of these materials, the exact formula is not necessarily important and it is likely that aqueous zincate solutions consist of mixtures.
The reaction is effected with zinc. The key zinc-intermediate formed is a carbenoid (iodomethyl)zinc iodide which reacts with alkenes to afford the cyclopropanated product. The rate of forming the active zinc species is increased via ultrasonication since the initial reaction occurs at the surface of the metal.
4, with a central zinc atom in the +2 or (II) valence state coordinated to four hydroxide groups. It has Sp3 hybridization. It is the most common of the zincate anions, and is often called just zincate. These names are also used for the salts containing that anion, such as sodium zincate Na 2 Zn(OH) 4 [2] and calcium zincate CaZn(OH) 4 ·2H 2 O [3]
The Reformatsky reaction (sometimes transliterated as Reformatskii reaction) is an organic reaction which condenses aldehydes or ketones with α-halo esters using metallic zinc to form β-hydroxy-esters: [1] [2] The Reformatsky reaction. The organozinc reagent, also called a 'Reformatsky enolate', is prepared by treating an alpha-halo ester ...
Zinc is a strong reducing agent with a standard redox potential of −0.76 V. Pure zinc tarnishes rapidly in air, rapidly forming a passive layer. The composition of this layer can be complex, but one constituent is probably basic zinc carbonate, Zn 5 (OH) 6 CO 3. [8] The reaction of zinc with water is slowed by this passive layer.
Zinc powder is sometimes used as a propellant in model rockets. [154] When a compressed mixture of 70% zinc and 30% sulfur powder is ignited there is a violent chemical reaction. [154] This produces zinc sulfide, together with large amounts of hot gas, heat, and light. [154]
Zinc cyanide is the inorganic compound with the formula Zn 2. It is a white solid that is used mainly for electroplating zinc but also has more specialized applications for the synthesis of organic compounds .
In enzymology, a Zn 2+-exporting ATPase (EC 3.6.3.5) is an enzyme that catalyzes the chemical reaction ATP + H 2 O + Zn 2+ in ⇌ {\displaystyle \rightleftharpoons } ADP + phosphate + Zn 2+ out The 3 substrates of this enzyme are ATP , H 2 O , and Zn 2+ , whereas its 3 products are ADP , phosphate , and Zn 2+ .