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Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
Energy shares the same unit of measurement with work (Joules) because the energy from the object doing work is transferred to the other objects it interacts with when work is being done. [17] The work–energy principle states that an increase in the kinetic energy of a rigid body is caused by an equal amount of positive work done on the body ...
Power is the rate with respect to time at which work is done; it is the time derivative of work: =, where P is power, W is work, and t is time. We will now show that the mechanical power generated by a force F on a body moving at the velocity v can be expressed as the product: P = d W d t = F ⋅ v {\displaystyle P={\frac {dW}{dt}}=\mathbf {F ...
Though a standardised value of 4.1860 J·cal −1 was established in the early 20th century, in the 1920s, it was ultimately realised that the constant is simply the specific heat of water, a quantity that varies with temperature between the values of 4.17 and 4.22 J·g −1 ·°C −1.
The typical efficiency of TEGs is around 5–8%, although it can be higher. Older devices used bimetallic junctions and were bulky. More recent devices use highly doped semiconductors made from bismuth telluride (Bi 2 Te 3), lead telluride (PbTe), [10] calcium manganese oxide (Ca 2 Mn 3 O 8), [11] [12] or combinations thereof, [13] depending on application temperature.
Electric power is the rate at which electric energy is transferred by an electric circuit. The SI unit of power is the watt, one joule per second. Electric power, like mechanical power, is the rate of doing work, measured in watts, and represented by the letter P. The term wattage is used colloquially to mean "electric power in watts."
The maximum work is thus regarded as the diminution of the free, or available, energy of the system (Gibbs free energy G at T = constant, P = constant or Helmholtz free energy F at T = constant, V = constant), whilst the heat given out is usually a measure of the diminution of the total energy of the system (internal energy).
The concept of free energy was developed by Hermann von Helmholtz, a German physicist, and first presented in 1882 in a lecture called "On the thermodynamics of chemical processes". [1] From the German word Arbeit (work), the International Union of Pure and Applied Chemistry (IUPAC) recommends the symbol A and the name Helmholtz energy. [2]