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The NaOH (caustic soda) and elevated temperature cause Fe 3 O 4 (black oxide) to form on the surface of the metal instead of Fe 2 O 3 (red oxide; rust). While it is physically denser than red oxide, the fresh black oxide is porous, so oil is then applied as post treatment to the heated part, which seals it by "sinking" into it.
Black oxide provides minimal protection against corrosion, unless also treated with a water-displacing oil to reduce wetting and galvanic action. In colloquial use, thin coatings of black oxide are often termed 'gun bluing', while heavier coatings are termed 'black oxide'. Both refer to the same chemical process for providing true gun bluing. [1]
Rust converters are chemical solutions or primers that can be applied directly to an iron or iron alloy surface to convert iron oxides into a protective chemical barrier. These compounds interact with iron oxides, especially iron(III) oxide , converting them into an adherent black layer ( black oxide ) that is more resistant to moisture and ...
Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe 2 O 3 ·nH 2 O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH) 3 ), and is typically associated with the corrosion of refined iron .
Iron or carbon steel metal exfoliates when oxidized under neutral or alkaline micro-electrolytic conditions; i.e., the iron oxide (actually ferric hydroxide or hydrated iron oxide, also known as rust) forms by anoxic anodic pits and large cathodic surface, these pits concentrate anions such as sulfate and chloride accelerating the underlying ...
Chelating rust removers offer a highly effective, nontoxic, acid-free, and biodegradable solution that binds to iron oxide (A.K.A. rust) and strips it away, making it easy to remove. You typically ...
Aluminium similarly forms a stable protective oxide layer which is why it does not "rust". (In contrast, some base metals, notably iron , oxidize readily to form a rough, porous coating of rust that adheres loosely, is of higher volume than the original displaced metal, and sloughs off readily; all of which permit & promote further oxidation.)
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