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3, which is the main component of commercial sodium silicate solutions. It is an ionic compound consisting of sodium cations Na + and the polymeric metasilicate anions [– SiO 2− 3 –] n. It is a colorless crystalline hygroscopic and deliquescent solid, soluble in water (giving an alkaline solution) but not in alcohols. [1]
Sodium silicate solutions can also be used as a spin-on adhesive layer to bond glass to glass [21] or a silicon dioxide–covered silicon wafer to one another. [22] Sodium silicate glass-to-glass bonding has the advantage that it is a low-temperature bonding technique, as opposed to fusion bonding. [21]
Impregnation of wood with a potassium silicate solution is an easy and low-cost way for rendering the woodwork of houses secure against catching fire. The woodwork is first saturated with a diluted and nearly neutral solution of potash silicate. After drying, one or two coats of a more concentrated solution are usually applied. [2]
In chemistry, a silicic acid (/ s ɪ ˈ l ɪ s ɪ k /) is any chemical compound containing the element silicon attached to oxide (=O) and hydroxyl (−OH) groups, with the general formula [H 2x SiO x+2] n or, equivalently, [SiO x (OH) 4−2x] n. [1] [2] Orthosilicic acid is a representative example.
Idealized structure of sodium metasilicate. Metasilicates are silicates containing ions of empirical formula SiO 2− 3. Common stoichiometries include M I 2 SiO 3 and M II SiO 3. Metasilicates can be cyclic, usually the hexamer (SiO 3) 12− 6 or chains (SiO 3)n 2−. [1] Common compounds containing metasilicate anion are: Inosilicates
Depiction of a metasilicate chain, emphasizing the tetrahedral silicate subunits. Alternative depiction of a metasilicate chain emphasizing the Si-O bonds. With two shared oxides bound to each silicon, cyclic or polymeric structures can result. The cyclic metasilicate ring Si 6 O 12− 18 is a hexamer of SiO 3 2-.
Calcium ions then react with the soluble sodium silicate gel to convert it into solid calcium silicate hydrates (C-S-H). The C-S-H forms a continuous poorly permeable coating at the external surface of the aggregate. The penetrated alkaline solution (NaOH / KOH) converts the remaining siliceous minerals into bulky soluble alkali silicate gel.
Sodium silicide (NaSi, Na 4 Si 4) is a binary inorganic compound consisting of sodium and silicon. It is a solid black or grey crystalline material. [1] Sodium silicide reacts readily with water yielding gaseous hydrogen and aqueous sodium silicate in an exothermic reaction (~175 kJ·mol −1): [2] 2 NaSi + 5 H 2 O → 5 H 2 + Na 2 Si 2 O 5