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Solid-phase electrical conductivity: Variable, [6] depending on the nature of the bonding: network solids in which all electrons are used for sigma bonds (e.g. diamond, quartz) are poor conductors, as there are no delocalized electrons. However, network solids with delocalized pi bonds (e.g. graphite) or dopants can exhibit metal-like conductivity.
The covalent bonds in this material form extended structures, but do not form a continuous network. With cross-linking, however, polymer networks can become continuous, and a series of materials spans the range from Cross-linked polyethylene , to rigid thermosetting resins, to hydrogen-rich amorphous solids, to vitreous carbon, diamond-like ...
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The structure of liquids, glasses and other non-crystalline solids is characterized by the absence of long-range order which defines crystalline materials. Liquids and amorphous solids do, however, possess a rich and varied array of short to medium range order, which originates from chemical bonding and related interactions.
A solid angle of π sr is one quarter of that subtended by all of space. When all the solid angles at the vertices of a tetrahedron are smaller than π sr, O lies inside the tetrahedron, and because the sum of distances from O to the vertices is a minimum, O coincides with the geometric median, M, of the vertices.
Carbon bonds with itself to form two covalent network solids. [2] Diamond's C-C bond has a distance of away from each carbon since , while graphite's C-C bond has a distance of away from each carbon since . Although both bonds are between the same pair of elements they can have different bond lengths.
The exchange mechanism of dissociative CANs requires a bond-breaking event prior to the formation of a new bond (i.e. an elimination/addition pathway). [13]Upon application of a stimulus, the equilibrium shifts to the dissociated state, resulting in a temporarily decreased cross-link density in the network.
A net of a regular dodecahedron The eleven nets of a cube. In geometry, a net of a polyhedron is an arrangement of non-overlapping edge-joined polygons in the plane which can be folded (along edges) to become the faces of the polyhedron.