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Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula Na 2 S 2 O 3 ·(H 2 O) x. Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water.
Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3. Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid , such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4 ) 2 S 2 O 3 .
Conversion of simple disulfides to thiosulfinates results in a considerable weakening of the S–S bond from about 47.8 to 28.0 kcal mol −1 for the S-S bond in PhS(O)SPh and from about 63.2 to 39.3 kcal mol −1 for the S-S bond in MeS(O)SMe, [14] with the consequence that most thiosulfinates are both unstable and quite reactive.
The advantages of this approach are that (i) thiosulfate is far less toxic than cyanide and (ii) that ore types that are refractory to gold cyanidation (e.g. carbonaceous or Carlin-type ores) can be leached by thiosulfate. One problem with this alternative process is the high consumption of thiosulfate, which is more expensive than cyanide.
The branched thiosulfate oxidation pathway, a mechanism in which water-insoluble globules of intermediate sulfur are formed during the oxidation of thiosulfate and sulfide. It is present in all the anoxygenic photolithotrophic green and purple sulfur bacteria, and the free-living as well as symbiotic strains of certain sulfur-chemolithotrophic ...
This compound, upon standing, isomerizes to additionally bond through a nitrogen atom. S 4 N 4 oxidatively adds to Vaska's complex ([Ir(Cl)(CO)(PPh 3) 2] to form a hexacoordinate iridium complex where the S 4 N 4 binds through two sulfur atoms and one nitrogen atom. [2] Dilute NaOH hydrolyzes S 4 N 4 as follows, yielding thiosulfate and ...
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MTSL is attached to proteins by reaction with thiol groups. The reaction exploits standard reactivity of thiosulfate esters. Methanesulfinate (CH 3 SO 2 −) is the leaving group: RSO 2 S-nitroxide + protein-SH → protein-S-S-nitroxide + RSO 2 H. The heterodisulfide bond to the cysteine residue is robust, enabling site-directed spin labelling.