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Penning ionization is a form of chemi-ionization, an ionization process involving reactions between neutral atoms or molecules. [1] [2] The Penning effect is put to practical use in applications such as gas-discharge neon lamps and fluorescent lamps, where the lamp is filled with a Penning mixture to improve the electrical characteristics of the lamps.
Gas phase ion chemistry is a field of science encompassed within both chemistry and physics. It is the science that studies ions and molecules in the gas phase, most often enabled by some form of mass spectrometry. By far the most important applications for this science is in studying the thermodynamics and kinetics of reactions.
A Penning mixture is a mixture of gases that is used in electric gas-discharge lamps. It is defined as a mixture of one inert gas with a minute amount of another gas, one that has lower ionization voltage than the main constituent. It is named after Frans Michel Penning. [1] [2]
Chemi-ionization is the formation of an ion through the reaction of a gas phase atom or molecule with another atom or molecule when the collision energy is below the energy required to ionize the reagents. [1] [2] The reaction may involve a reagent in an excited state [3] or may result in the formation of a new chemical bond.
The basic element of the common ion pump is a Penning trap. [6] A swirling cloud of electrons produced by an electric discharge is temporarily stored in the anode region of a Penning trap. These electrons ionize incoming gas atoms and molecules. The resultant swirling ions are accelerated to strike a chemically active cathode (usually titanium ...
Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A −•.The reaction is + where the M over the arrow denotes that to conserve energy and momentum a third body is required (the molecularity of the reaction is three).
Sample preparation for PI includes first ensuring the sample is in the gas phase. PI ionizes molecules by exciting the sample molecules with photons of light. This method only works if the sample and other components in the gas phase are excited by different wavelengths of light. It is important when preparing the sample, or photon source, that ...
The ionization with its characteristics (see above) is not influenced by the coupling, allowing the same ionization method to be used for different chromatography couplings. The ability to couple gas chromatography with a low-fragmentation ionization technique on an LC-MS, for example, can be utilized in the analysis of saturated hydrocarbons.
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