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In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (a fluid such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrinsic permeability , and the materials' mass diffusivity . [ 1 ]
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The term pervaporation is a portmanteau of the two steps of the process: (a) permeation through the membrane by the permeate, then (b) its evaporation into the vapor phase. . This process is used by a number of industries for several different processes, including purification and analysis, due to its simplicity and in-line natu
Tracer diffusion and Self-diffusion, which is a spontaneous mixing of molecules taking place in the absence of concentration (or chemical potential) gradient. This type of diffusion can be followed using isotopic tracers, hence the name. The tracer diffusion is usually assumed to be identical to self-diffusion (assuming no significant isotopic ...
Permeability is affected by the penetrant size. Larger gas molecules have a lower diffusion coefficient. The polymer chain flexibility and free volume in the polymer of the membrane material influence the diffusion coefficient, as the space within the permeable membrane must be large enough for the gas molecules to diffuse across.
The concept of permeability is of importance in determining the flow characteristics of hydrocarbons in oil and gas reservoirs, [4] and of groundwater in aquifers. [5]For a rock to be considered as an exploitable hydrocarbon reservoir without stimulation, its permeability must be greater than approximately 100 md (depending on the nature of the hydrocarbon – gas reservoirs with lower ...
Multicomponent diffusion is diffusion in mixtures, and diffusiophoresis is the special case where we are interested in the movement of one species that is usually a colloidal particle, in a gradient of a much smaller species, such as dissolved salt such as sodium chloride in water. or a miscible liquid, such as ethanol in water.
The Nernst–Planck equation is a conservation of mass equation used to describe the motion of a charged chemical species in a fluid medium. It extends Fick's law of diffusion for the case where the diffusing particles are also moved with respect to the fluid by electrostatic forces.