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Cyanamide can be regarded as a functional single carbon fragment which can react as an electrophile or nucleophile. The main reaction exhibited by cyanamide involves additions of compounds containing an acidic proton. Water, hydrogen sulfide, and hydrogen selenide react with cyanamide to give urea, thiourea, and selenourea, respectively:
Thiourea (/ ˌ θ aɪ. oʊ j ʊəˈr iː. ə,-ˈ jʊər i-/) [2] [3] [4] is an organosulfur compound with the formula SC(NH 2) 2 and the structure H 2 N−C(=S)−NH 2.It is structurally similar to urea (H 2 N−C(=O)−NH 2), except that the oxygen atom is replaced by a sulfur atom (as implied by the thio-prefix); however, the properties of urea and thiourea differ significantly.
N,N′-unsubstituted thioureas can be prepared by treating the corresponding cyanamide with hydrogen sulfide or similar sulfide sources. [4] Organic ammonium salts react with potassium thiocyanate as the source of the thiocarbonyl (C=S). [5] Alternatively, N,N′-disubstituted thioureas can be prepared by coupling two amines with thiophosgene: [6]
Hydrogen sulfide is a chemical compound with the formula H 2 S. It is a colorless chalcogen-hydride gas , and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs . [ 11 ]
The conversion is conducted in slurries. For this reason, most commercial calcium cyanamide is sold as an aqueous solution. Thiourea can be produced by the reaction of hydrogen sulfide with calcium cyanamide in the presence of carbon dioxide. [15] Calcium cyanamide is also used as a wire-fed alloy in steelmaking to introduce nitrogen into the ...
Removal of cyanide from cassava in Nigeria. Cyanides are produced by certain bacteria, fungi, and algae.It is an antifeedant in a number of plants. Cyanides are found in substantial amounts in certain seeds and fruit stones, e.g., those of bitter almonds, apricots, apples, and peaches. [5]
Cyanogen is typically generated from cyanide compounds. One laboratory method entails thermal decomposition of mercuric cyanide: . 2 Hg(CN) 2 → (CN) 2 + Hg 2 (CN) 2 Or, one can combine solutions of copper(II) salts (such as copper(II) sulfate) with cyanides; an unstable copper(II) cyanide is formed which rapidly decomposes into copper(I) cyanide and cyanogen.
Some compounds described as salts of the sulfide dianion contain primarily hydrosulfide. For example, the hydrated form of sodium sulfide, nominally with the formula Na 2 S · 9 H 2 O, is better described as NaSH · NaOH · 8 H 2 O. The UV–visible spectrum of septic sewage from three different sites.