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Worldwide production of R-22 in 2008 was about 800 Gg per year, up from about 450 Gg per year in 1998, with most production in developing countries. [2] R-22 use is being phased out in developing countries, where it is largely used for air conditioning applications. R-22 is prepared from chloroform: HCCl 3 + 2 HF → HCF 2 Cl + 2 HCl
Chlorodifluoromethane (R-22 or HCFC-22), a type of Freon. [9] [10] Dichlorodifluoromethane (R-12 or CFC-12), the most commonly used Freon brand refrigerant prior to its ban in many countries in 1996 and total ban in 2010. 1,1,1,2-Tetrafluoroethane (R-134a or HFC-134a), one of the main replacements for the formerly widespread R-12.
According to ASHRAE standard 34, the R-number of a chemical refrigerant is assigned systematically according to its molecular structure and has between two and four digits. If there are carbon -carbon multiple bonds , there are four digits in all: the number of these bonds is the first digit and the number of carbon atoms minus one (C-1) is next.
Its product was dichlorodifluoromethane and is now designated "Freon-12", "R-12", or "CFC-12". The number after the R is a refrigerant class number developed by DuPont to systematically identify single halogenated hydrocarbons, as well as other refrigerants besides halocarbons. DuPont introduced phenothiazine as an insecticide in 1935. [19]
Mineral oil used with R-12 is not compatible with R-134a. Some oils designed for conversion to R-134a are advertised as compatible with residual R-12 mineral oil. Illegal replacements for R-12 include highly flammable hydrocarbon blends such as HC-12a , the flammability of which has caused injuries and deaths.
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The List of painters in the National Gallery of Art is a list of the named artists in the National Gallery of Art, Washington, D.C. whose works there comprise oil paintings, gouaches, tempera paintings, and pastels. The online collection contains roughly 4,000 paintings by 1,000 artists, but only named painters with the previously mentioned ...
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