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Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive . A common concentration is 49% (48-52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature.
Hydrogen fluoride is typically produced by the reaction between sulfuric acid and pure grades of the mineral fluorite: [14] CaF 2 + H 2 SO 4 → 2 HF + CaSO 4. About 20% of manufactured HF is a byproduct of fertilizer production, which generates hexafluorosilicic acid. This acid can be degraded to release HF thermally and by hydrolysis: H 2 SiF ...
Sodium bifluoride reacts with water or moist skin to produce hydrofluoric acid. It also gives off hydrofluoric acid and hydrogen gas when it is heated to a gaseous state. The chemical can decompose upon contact with strong acids, strong bases, metal, water, or glass. [3] Sodium bifluoride also engages in violent reactions with chromyl chloride ...
This neutralization reaction forms hydrogen fluoride (HF), the conjugate acid of fluoride. In aqueous solution, fluoride has a pK b value of 10.8. It is therefore a weak base, and tends to remain as the fluoride ion rather than generating a substantial amount of hydrogen fluoride. That is, the following equilibrium favours the left-hand side in ...
In water, ammonium bifluoride exists in chemical equilibrium with hydrofluoric acid and heating releases hydrogen fluoride gas. [9] Consequently, there is an equivalent toxicological risk as is present with hydrofluoric acid, and the same safety precautions apply. [10] [9] Ammonium bifluoride is used in some automotive wheel cleaning products.
The salt was prepared by Edmond Frémy by treating potassium carbonate or potassium hydroxide with hydrofluoric acid: 2 HF + KOH → K[HF 2] + H 2 O. With one more equivalent of HF, K[H 2 F 3] (CAS RN 12178-06-2, m.p. 71.7 °C [4]) is produced: HF + K[HF 2] → K[H 2 F 3] Thermal decomposition of K[HF 2] gives hydrogen fluoride: K[HF 2] → HF + KF
The bifluoride ion has a linear, centrosymmetric structure (D ∞h symmetry), with an F−H bond length of 114 pm. [1] The bond strength is estimated to be greater than 155 kJ/mol. [2] In molecular orbital theory, the atoms are modeled to be held together by a 3-center 4-electron bond (symmetrical hydrogen bond), [3] in a sort of hybrid between a hydrogen bond and a covalent bond.
Rubidium fluoride is a white crystalline substance with a cubic crystal structure that looks very similar to common salt (NaCl). The crystals belong to the space group Fm3m (space group no. 225) with the lattice parameter a = 565 pm and four formula units per unit cell. [2] The refractive index of the crystals is nD = 1.398. [2]