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184.5 °c (364.1 °f; 457.7 k) Benzyl bromide is an isomer, which has a bromine substituted for one of the hydrogens of toluene 's methyl group, and it is sometimes named α-bromotoluene. Preparation
3-Nitrotoluene or meta-nitrotoluene is an organic compound with the formula CH 3 C 6 H 4 NO 2. It is one of three isomers of nitrotoluene. A yellow liquid, it is used in the manufacture of meta-toluidine, which is an intermediate in the production of various dyes. [3]
The reaction mechanism [8] of the Bartoli indole synthesis is illustrated below using o-nitrotoluene (1) and propenyl Grignard (2) to form 3,7-dimethylindole (13). The mechanism of the Bartoli indole synthesis. The mechanism begins by the addition of the Grignard reagent (2) onto the nitroarene (1) to form intermediate 3.
The first step of the synthesis is the condensation of o-nitrotoluene 1 with a diethyl oxalate 2 to give ethyl o-nitrophenylpyruvate 3. The reductive cyclization of 3 with zinc in acetic acid gives indole-2-carboxylic acid 4. If desired, 4 can be decarboxylated with heat to give indole 5.
o-Toluidine is produced industrially by nitration of toluene to give a mixture of nitrotoluenes, favoring the ortho isomer. This mixture is separated by distillation. 2-Nitrotoluene is hydrogenated to give o-toluidine. [2] The conversion of o-toluidine to the diazonium salt gives access to the 2-bromo, 2-cyano-, and 2-chlorotoluene derivatives.
Mononitrotoluene or nitrotoluene (MNT or NT), is any of three organic compounds with the formula C 6 H 4 (CH 3)(NO 2). [1] They can be viewed as nitro derivatives of toluene or as methylated derivatives of nitrobenzene. Mononitrotoluene comes in three isomers, differing by the relative position of the methyl and nitro groups. All are pale ...
KFC’s “finger lickin’ good” slogan usually refers to chicken, but it’s taking on different meaning at its newest location. Sauce and dips are the star at “Saucy,” a prototype opening ...
4-Nitrotoluene This page was last edited on 30 January 2024, at 19:32 (UTC). Text is available under the Creative Commons Attribution-ShareAlike 4.0 License ...