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A primary standard in metrology is a standard that is sufficiently accurate such that it is not calibrated by or subordinate to other standards. Primary standards are defined via other quantities like length, mass and time. Primary standards are used to calibrate other standards referred to as working standards. [1] [2] See Hierarchy of Standards.
A standard solution created from a secondary standard cannot have its concentration accurately known without stoichiometric analysis against a primary standard. An example of a secondary standard is sodium hydroxide, a hydroscopic compound that is highly reactive with its surroundings. The concentration of a standard solution made with sodium ...
An example of a primary standard was the international prototype of the kilogram (IPK) which was the master kilogram and the primary mass standard for the International System of Units (SI). The IPK is a one kilogram mass of a platinum-iridium alloy maintained by the International Bureau of Weights and Measures (BIPM) in Sèvres, France.
Azeotropic, or "constant-boiling", hydrochloric acid (roughly 20.2%) can be used as a primary standard in quantitative analysis, although its exact concentration depends on the atmospheric pressure when it is prepared. [34]
Secondary reference standards: Reference standards calibrated against and traceable to primary WHO materials and intended for use in routine tests; Reference reagent: a WHO reference standard, the activity of which is defined by WHO in terms of a unit; For chemical substances some pharmacopoeias [10] use the WHO terms [11]
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
amount of substance "The mole, symbol mol, is the SI unit of amount of substance. One mole contains exactly 6.022 140 76 × 10 23 elementary entities. This number is the fixed numerical value of the Avogadro constant, N A, when expressed in the unit mol −1 and is called the Avogadro number.
Pressure. A U tube filled with water is a primary instrument as the water column differential is unchangeable as water is a basic physical substance. It is accurate due to its nature. Similarly a liquid in glass thermometer is a primary instrument as temperature change causes change in height of mercury column differential of which is unchangeable.