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Fluorine is a chemical element; it has symbol F and atomic number 9. It is the lightest halogen [ note 1 ] and exists at standard conditions as pale yellow diatomic gas. Fluorine is extremely reactive as it reacts with all other elements except for the light inert gases .
F and 26m F). Only fluorine-19 is stable and naturally occurring in more than trace quantities; therefore, fluorine is a monoisotopic and mononuclidic element. The longest-lived radioisotope is 18 F; it has a half-life of 109.734(8) min. All other fluorine isotopes have half-lives of less than a minute, and most of those less than a second.
Fluorine, in the form of fluoride, is considered to be a micronutrient for human health, necessary to prevent dental cavities, and to promote healthy bone growth. [28] The tea plant (Camellia sinensis L.) is a known accumulator of fluorine compounds, released upon forming infusions such as the common beverage. The fluorine compounds decompose ...
Fluorapatite (Ca 5 (PO 4) 3 F) is mined along with other apatites for its phosphate content and is used mostly for production of fertilizers. Most of the Earth's fluorine is bound in this mineral, but because the percentage within the mineral is low (3.5%), the fluorine is discarded as waste. Only in the United States is there significant recovery.
The covalent radius of fluorine of about 71 picometers found in F 2 molecules is significantly larger than that in other compounds because of this weak bonding between the two fluorine atoms. [9] This is a result of the relatively large electron and internuclear repulsions, combined with a relatively small overlap of bonding orbitals arising ...
The most common F-gases are hydrofluorocarbons (HFCs), which contain hydrogen, fluorine, and carbon. They are used in a multitude of applications including commercial refrigeration , industrial refrigeration, air-conditioning systems, heat pump equipment, and as blowing agents for foams, fire extinguishants, aerosol propellants, and solvents.
Fluorine solidifies at −220 °C (−363 °F) [5] into a cubic structure, called beta-fluorine. This phase is transparent and soft, with significant disorder of the molecules; its density is 1.70 g/cm 3. At −228 °C (−378 °F) fluorine undergoes a solid–solid phase transition into a monoclinic structure called alpha-fluorine.
Atoms are labelled with the sulfur atom connected to three fluorine atoms as S hyp (for hypervalent) and S top. The fluorine atoms are labelled F top attached to S top, and on the hypervalent S atom: F cis, the closest F atom to F top, F trans the furthest away F atom from F top, and F eq [3] Carlowitz first determined the structure in 1983. [3]
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