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At pH 1 or lower, the phosphoric acid is practically undissociated. Around pH 4.7 (mid-way between the first two pK a values) the dihydrogen phosphate ion, [H 2 PO 4] −, is practically the only species present. Around pH 9.8 (mid-way between the second and third pK a values) the monohydrogen phosphate ion, [HPO 4] 2−, is the only species ...
A phosphate phosphite is a chemical compound or salt that contains phosphate and phosphite anions (PO 3 3-and PO 4 3-). These are mixed anion compounds or mixed valence compounds. Some have third anions. Phosphate phosphites frequently occur as metal organic framework (MOF) compounds which are of research interest for gas storage, detection or ...
The term phosphate is also used in organic chemistry for the functional groups that result when one or more of the hydrogens are replaced by bonds to other groups. These acids, together with their salts and esters , include some of the best-known compounds of phosphorus, of high importance in biochemistry , mineralogy , agriculture , pharmacy ...
Some bonding modes in phosphate complexes. Transition metal phosphate complexes are coordination complexes with one or more phosphate ligands. Phosphate binds to metals through one, two, three, or all four oxygen atoms. The bidentate coordination mode is common. The second and third pK a 's of phosphoric acid, pK a2 and pK a3, are 7.2 and 12.37 ...
With metal cations, phosphate forms a variety of salts. These solids are polymeric, featuring P-O-M linkages. When the metal cation has a charge of 2+ or 3+, the salts are generally insoluble, hence they exist as common minerals. Many phosphate salts are derived from hydrogen phosphate (HPO 4 2−). PCl 5 and PF 5 are common compounds.
Phosphate is also used in animal feed supplements, food preservatives, anti-corrosion agents, cosmetics, fungicides, ceramics, water treatment and metallurgy. The production of fertilizer is the largest source responsible for minerals mined for their phosphate content.
The acid and metal reaction also creates iron phosphate locally which may also be deposited. When depositing zinc phosphate or manganese phosphate the additional iron phosphate may be an undesired impurity. The bath often includes an oxidizer, such as sodium nitrite (NaNO 2), to consume the hydrogen gas (H
Zinc phosphate is an inorganic compound with the formula Zn 3 (PO 4) 2. This white powder is widely used as a corrosion resistant coating on metal surfaces either as part of an electroplating process or applied as a primer pigment (see also red lead ).