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The combination of urea and ammonium nitrate has an extremely low critical relative humidity (18% at 30 °C) and can therefore only be used in liquid fertilizers. The most commonly used grade of these fertilizer solutions is UAN 32.0.0 (32%N) known as UN32 or UN-32, which consists of 45% ammonium nitrate , 35% urea and only 20% water.
Urea plant using ammonium carbamate briquettes, Fixed Nitrogen Research Laboratory, ca. 1930 Carl Bosch, 1927. The Bosch–Meiser process is an industrial process, which was patented in 1922 [1] and named after its discoverers, the German chemists Carl Bosch and Wilhelm Meiser [2] for the large-scale manufacturing of urea, a valuable nitrogenous chemical.
Since urea is not an oxidizer at standard temperature and pressure, it is safer to handle and less of a security risk than other common nitrogen fertilizers, such as ammonium nitrate. However, if urea is applied to the soil surface, a meaningful fraction of applied fertilizer nitrogen may be lost to the atmosphere as ammonia gas; this only ...
Urea is highly soluble in water and is therefore also very suitable for use in fertilizer solutions (in combination with ammonium nitrate: UAN), e.g., in 'foliar feed' fertilizers. For fertilizer use, granules are preferred over prills because of their narrower particle size distribution, which is an advantage for mechanical application.
Synthetic nitrogen fertilizers, such as ammonium nitrate and urea, are commonly applied to crops to replenish soil nitrogen levels and enhance crop productivity [3] These fertilizers provide readily available nitrogen for plant uptake, thereby promoting vigorous vegetative growth and improving yields.
The conversion from ammonia to urea happens in five main steps. The first is needed for ammonia to enter the cycle and the following four are all a part of the cycle itself. To enter the cycle, ammonia is converted to carbamoyl phosphate. The urea cycle consists of four enzymatic reactions: one mitochondrial and three cytosolic.
Urea nitrate is produced in one step by reaction of urea with nitric acid. This is an exothermic reaction, so steps must be taken to control the temperature. It was discovered in 1797 by William Cruickshank, [4] inventor of the Chloralkali process. Urea nitrate explosions may be initiated using a blasting cap. [3]
Nearly 97% of South Korea's urea imports came from China between January and September. In 2015, South Korea had made it mandatory for diesel cars to use urea solutions to control emissions, a move that now impacts 40% of registered vehicles. Diesel vehicles made since 2015 were required to be fitted with SCR systems. [28]