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Sodium sulfide is a chemical compound with the formula Na 2 S, or more commonly its hydrate Na 2 S·9H 2 O.Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline mass, in flake form, or as a fused solid.
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Below 114 K, the structure becomes monoclinic. The analogous rubidium and potassium compounds behave similarly. [1] NaSH has a relatively low melting point of 350 °C. In addition to the aforementioned anhydrous forms, it can be obtained as two different hydrates, NaSH·2H 2 O and NaSH·3H 2 O. These three species are all colorless and behave ...
BF 3 + OMe 2 → BF 3 OMe 2. Both BF 4 − and BF 3 OMe 2 are Lewis base adducts of boron trifluoride. Many adducts violate the octet rule, such as the triiodide anion: I 2 + I − → I − 3. The variability of the colors of iodine solutions reflects the variable abilities of the solvent to form adducts with the Lewis acid I 2.
4 NaClO + Na 2 S 2 O 3 + 2 NaOH → 4 NaCl + 2 Na 2 SO 4 + H 2 O. Similarly, sodium thiosulfate reacts with bromine, removing the free bromine from the solution. Solutions of sodium thiosulfate are commonly used as a precaution in chemistry laboratories when working with bromine and for the safe disposal of bromine, iodine, or other strong ...
Sodium metal is highly reducing, with the standard reduction potential for the Na + /Na couple being −2.71 volts, [3] though potassium and lithium have even more negative potentials. [4] The thermal, fluidic, chemical, and nuclear properties of molten sodium metal have caused it to be one of the main coolants of choice for the fast breeder ...
Hargreaves: 4 NaCl + 2 SO 2 + O 2 + 2 H 2 O → 4 HCl + 2 Na 2 SO 4. The second major production of sodium sulfate are the processes where surplus sodium hydroxide is neutralised by sulfuric acid to obtain sulfate (SO 2− 4) by using copper sulfate (CuSO 4) (as historically applied on a large scale in the production of rayon by using copper(II ...
Structure of anhydrous sodium sulfite. Sodium sulfite can be prepared by treating a solution of sodium hydroxide with sulfur dioxide. When conducted in warm water, Na 2 SO 3 initially precipitates as a white solid. With more SO 2, the solid dissolves to give the disulfite, which crystallizes upon cooling. [2] SO 2 + 2 NaOH → Na 2 SO 3 + H 2 O