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  2. Standard electrode potential (data page) - Wikipedia

    en.wikipedia.org/wiki/Standard_electrode...

    The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: . Temperature 298.15 K (25.00 °C; 77.00 °F); ...

  3. SN2 reaction - Wikipedia

    en.wikipedia.org/wiki/SN2_reaction

    Competition experiment between SN2 and E2. With ethyl bromide, the reaction product is predominantly the substitution product. As steric hindrance around the electrophilic center increases, as with isobutyl bromide, substitution is disfavored and elimination is the predominant reaction. Other factors favoring elimination are the strength of the ...

  4. List of United States Navy enlisted rates - Wikipedia

    en.wikipedia.org/wiki/List_of_United_States_Navy...

    The badge of the Master Chief Petty Officer of the U.S. Navy, worn on a service dress blue uniform's sleeve. In the United States Navy, a rate is the military rank of an enlisted sailor, indicating where the sailor stands within the chain of command, and also defining one's pay grade.

  5. Solvolysis - Wikipedia

    en.wikipedia.org/wiki/Solvolysis

    In chemistry, solvolysis is a type of nucleophilic substitution (S N 1/S N 2) or elimination where the nucleophile is a solvent molecule. [1] Characteristic of S N 1 reactions, solvolysis of a chiral reactant affords the racemate.

  6. SN1 reaction - Wikipedia

    en.wikipedia.org/wiki/SN1_reaction

    If the reaction is performed under warm or hot conditions (which favor an increase in entropy), E1 elimination is likely to predominate, leading to formation of an alkene. At lower temperatures, S N 1 and E1 reactions are competitive reactions and it becomes difficult to favor one over the other. Even if the reaction is performed cold, some ...

  7. United States Army enlisted rank insignia - Wikipedia

    en.wikipedia.org/wiki/United_States_Army...

    The rank of private was divided into two ranks of private (Grade E1 and Grade E2), and private first class (Grade E3). Corporal was regraded as Grade E4. Sergeant (Grade E5) was a career soldier rank and its former three-chevron insignia was abolished and replaced with the three chevrons and an arc of the rank of staff sergeant.

  8. Hammett equation - Wikipedia

    en.wikipedia.org/wiki/Hammett_equation

    For example, the substituent may determine the mechanism to be an SN1 type reaction over a SN2 type reaction, in which case the resulting Hammett plot will indicate a rate acceleration due to an EDG, thus elucidating the mechanism of the reaction. Another deviation from the regular Hammett equation is explained by the charge of nucleophile.

  9. Elimination reaction - Wikipedia

    en.wikipedia.org/wiki/Elimination_reaction

    Scheme 2. E1 reaction mechanism. An example in scheme 2 is the reaction of tert-butylbromide with potassium ethoxide in ethanol. E1 eliminations happen with highly substituted alkyl halides for two main reasons. Highly substituted alkyl halides are bulky, limiting the room for the E2 one-step mechanism; therefore, the two-step E1 mechanism is ...