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Anthropogenic (man-made) sources of arsenic, like the natural sources, are mainly arsenic oxides and the associated anions. Man-made sources of arsenic, include wastes from mineral processing, swine and poultry farms. [16] For example, many ores, especially sulfide minerals, are contaminated with arsenic, which is released in roasting (burning ...
Inorganic arsenic and its compounds, upon entering the food chain, are progressively metabolized to a less toxic form of arsenic through a process of methylation. [7] Organoarsenic compounds arise via biomethylation of inorganic arsenic compounds, [ 8 ] via processes mediated by enzymes related to vitamin B 12 . [ 9 ]
Arsenic is also found in food, water, soil, and air. [132] Arsenic is absorbed by all plants, but is more concentrated in leafy vegetables, rice, apple and grape juice, and seafood. [133] An additional route of exposure is inhalation of atmospheric gases and dusts. [134]
Arsenic is a ubiquitous naturally occurring chemical element, and the 20th most common element on Earth. [13] Arsenic levels in the groundwater vary from around 0.5 parts per billion to 5000 parts per billion, depending on an area's geologic features, and possible presence on industrial waste.
Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
The FDA does have suggested limits for chocolate and sugar-based candy but only for children. According to the California guidelines, the threshold for heavy metals in foods is 0.5 micrograms a day.
Foods such as the flesh of fatty fish are good natural sources of vitamin D; there are few other foods where it naturally appears in significant amounts. [2] In the U.S. and other countries, cow's milk and plant-based milk substitutes are fortified with vitamin D 3, as are many breakfast cereals.
Calcium arsenate is commonly prepared from disodium hydrogen arsenate and calcium chloride: 2 Na 2 H[AsO 4] + 3 CaCl 2 → 4 NaCl + Ca 3 [AsO 4] 2 + 2 HCl. In the 1920s, it was made in large vats by mixing calcium oxide and arsenic oxide. [6] In the United States, 1360 metric tons were produced in 1919, 4540 in 1920, and 7270 in 1922. [1]