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Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
In chemistry, the mesomeric effect (or resonance effect) is a property of substituents or functional groups in a chemical compound. It is defined as the polarity produced in the molecule by the interaction of two pi bonds or between a pi bond and lone pair of electrons present on an adjacent atom. [ 1 ]
In chemistry, the electromeric effect is a molecular polarization occurring by an intramolecular electron displacement, characterized by the substitution of one electron pair for another within the same atomic octet of electrons.
Hyperconjugation can be used to rationalize a variety of chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of exocyclic carbonyl groups, and the relative stability of substituted carbocations and substituted carbon centred radicals, and the thermodynamic Zaitsev's rule for alkene stability.
An electron-withdrawing group (EWG) is a group or atom that has the ability to draw electron density toward itself and away from other adjacent atoms. [1] This electron density transfer is often achieved by resonance or inductive effects.
In physics, a Feshbach resonance can occur upon collision of two slow atoms, when they temporarily stick together forming an unstable compound with short lifetime (so-called resonance). [1] It is a feature of many-body systems in which a bound state is achieved if the coupling(s) between at least one internal degree of freedom and the reaction ...
The Purcell effect is the enhancement of a quantum system's spontaneous emission rate by its environment. In the 1940s Edward Mills Purcell discovered the enhancement of spontaneous emission rates of atoms when they are incorporated into a resonant cavity.
The Mössbauer effect, or recoilless nuclear resonance fluorescence, is a physical phenomenon discovered by Rudolf Mössbauer in 1958. It involves the resonant and recoil -free emission and absorption of gamma radiation by atomic nuclei bound in a solid.
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