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Cumene is oxidized in air, which removes the tertiary benzylic hydrogen from cumene and hence forms a cumene radical: The cumene radical then bonds with an oxygen molecule to give cumene peroxide radical, which in turn forms cumene hydroperoxide (C 6 H 5 C(CH 3) 2 O 2 H) by abstracting a benzylic hydrogen from another cumene molecule. This ...
Cumene (isopropylbenzene) is an organic compound that contains a benzene ring with an isopropyl substituent. It is a constituent of crude oil and refined fuels. It is a flammable colorless liquid that has a boiling point of 152 °C.
in the cumene process, isopropylbenzene undergoes autoxidation to give cumene hydroperoxide. This compound is then converted to phenol and acetone, both commodity chemicals. are made from benzene and propylene. Many variations of this reaction have been developed, e.g. use of diisopropylbenzene as a substrate.
In commercial applications, the alkylating agents are generally alkenes, some of the largest scale reactions practiced in industry.Such alkylations are of major industrial importance, e.g. for the production of ethylbenzene, the precursor to polystyrene, from benzene and ethylene and for the production of cumene from benzene and propene in cumene process:
Acetophenone is formed as a byproduct of the cumene process, the industrial route for the synthesis of phenol and acetone.In the Hock rearrangement of isopropylbenzene hydroperoxide, migration of a methyl group rather than the phenyl group gives acetophenone and methanol as a result of an alternate rearrangement of the intermediate:
Cumene hydroperoxide is the organic compound with the formula C 6 H 5 C(CH 3) 2 OOH; this oily liquid is classified as an organic hydroperoxide. [2] Products of decomposition of cumene hydroperoxide are methylstyrene, acetophenone, and 2-phenylpropan-2-ol. [3] It is produced by treatment of cumene with oxygen, an autoxidation.
Soluble in ethanol and benzene [3] Refractive index (n D) 1.49146 (20 °C) [4] Hazards GHS labelling: ... 2-Phenyl-2-propanol is the main metabolite of cumene, ...
n-Propylbenzene is an aromatic hydrocarbon with the formula C 6 H 5 CH 2 CH 2 CH 3.The molecule consists of a propyl group attached to a phenyl ring. It is a colorless liquid. A more common structural isomer of this compound is cumene.