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The cumene radical then bonds with an oxygen molecule to give cumene peroxide radical, which in turn forms cumene hydroperoxide (C 6 H 5 C(CH 3) 2 O 2 H) by abstracting a benzylic hydrogen from another cumene molecule. This latter cumene converts into cumene radical and feeds back into subsequent chain formations of cumene hydroperoxides.
Cumene (isopropylbenzene) is an organic compound that contains a benzene ring with an isopropyl substituent. It is a constituent of crude oil and refined fuels. It is a flammable colorless liquid that has a boiling point of 152 °C.
In commercial applications, the alkylating agents are generally alkenes, some of the largest scale reactions practiced in industry.Such alkylations are of major industrial importance, e.g. for the production of ethylbenzene, the precursor to polystyrene, from benzene and ethylene and for the production of cumene from benzene and propene in cumene process:
Cumene hydroperoxide is an intermediate in the cumene process for producing phenol and acetone from benzene and propene. Cumene hydroperoxide is a radical initiator for production of acrylates. [5] Cumene hydroperoxide is involved as an organic peroxide in the production of propylene oxide by the oxidation of propene. This technology was ...
In 1975 the Vapor Recovery Gasoline Nozzle was an improvement on the idea of the original gasoline nozzle delivery system. The improved idea was the brain child of Mark Maine of San Diego, California, where Mark was a gas station attendant at a corporate owned and operated Chevron U.S.A. service station.
Normally these cumene radicals are converted to cumene hydroperoxide, however they can also undergo radical disproportionation to form AMS. Although this is only a minor side reaction, the cumene process is run at such a large scale that the recovery of AMS is commercially viable and satisfies much of the global demand. AMS can also be produced ...
n-Propylbenzene is an aromatic hydrocarbon with the formula C 6 H 5 CH 2 CH 2 CH 3.The molecule consists of a propyl group attached to a phenyl ring. It is a colorless liquid. A more common structural isomer of this compound is cumene.
Accounting for 95% of production (2003) is the cumene process, also called Hock process. It involves the partial oxidation of cumene (isopropylbenzene) via the Hock rearrangement: [8] Compared to most other processes, the cumene process uses mild conditions and inexpensive raw materials. For the process to be economical, both phenol and the ...