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Sulfate attack typically happens to ground floor slabs in contact with soils containing a source of sulfates. [2] Sulfates dissolved by ground moisture migrate into the concrete of the slab where they react with different mineral phases of the hardened cement paste. The attack arises from soils containing SO 2−
AFm form inter alia when tricalcium aluminate 3CaO·Al 2 O 3, or C 3 A in CCN, reacts with dissolved calcium sulfate (CaSO 4), or calcium carbonate (CaCO 3). As the sulfate form is the dominant one in AFm phases in the hardened cement paste (HCP) in concrete, AFm is often simply referred to as Aluminate Ferrite monosulfate or calcium aluminate ...
Calcium aluminates can form complex salts in combination with different types of anions.Two series of calcium aluminates are known in cement chemistry: AFm and AFt phases, being respectively mono- or tri-substituted with a given divalent anion X (e.g. SO 2− 4, CO 2− 3, or hosting a divalent impurity such as SeO 2− 4 [3]...), or with two units of a monovalent anion, e.g. OH −, Cl − ...
Ettringite is the most common and prominent member of the AFt group (X in this case denoting sulfate), and often simply called Alumina Ferrite tri-sulfate (AFt). AFm: abbreviation for "alumina, ferric oxide, mono-substituted" or (Al 2 O 3 − Fe 2 O 3 − mono). It represents another group of calcium aluminate hydrates with general formula [Ca ...
This reaction is expansive, and can disrupt mature concrete. Where concrete is to be placed in contact with, for example, sulfate-laden ground waters, either a "sulfate-resisting" cement (with low levels of tricalcium aluminate) is used, or slag is added to the cement or to the concrete mix. The slag contributes sufficient aluminium to suppress ...
4 AF) (white) and tricalcium aluminate (C 3 A) (grey) occupying interstitial space between alite (C 3 S) (blue) and belite (C 2 S) (orange) crystals. These are false (interference) colors. Calcium aluminoferrite (Ca 2 (Al,Fe) 2 O 5) is a dark brown crystalline phase commonly found in cements. In the cement industry it is termed tetra-calcium ...
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