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The fit line is then the line y = mx + b with coefficients m and b in slope–intercept form. [12] As Sen observed, this choice of slope makes the Kendall tau rank correlation coefficient become approximately zero, when it is used to compare the values x i with their associated residuals y i − mx i − b. Intuitively, this suggests that how ...
The simplest is the slope-intercept form: = +, from which one can immediately see the slope a and the initial value () =, which is the y-intercept of the graph = (). Given a slope a and one known value () =, we write the point-slope form:
In enzyme kinetics, a secondary plot uses the intercept or slope from several Lineweaver–Burk plots to find additional kinetic constants. [1] [2]For example, when a set of v by [S] curves from an enzyme with a ping–pong mechanism (varying substrate A, fixed substrate B) are plotted in a Lineweaver–Burk plot, a set of parallel lines will be produced.
A slope greater than one thus indicates positively cooperative binding between the receptor and the ligand, while a slope less than one indicates negatively cooperative binding. Transformations of equations into linear forms such as this were very useful before the widespread use of computers, as they allowed researchers to determine parameters ...
Effects of different types of inhibition on the double-reciprocal plot. When used for determining the type of enzyme inhibition, the Lineweaver–Burk plot can distinguish between competitive, pure non-competitive and uncompetitive inhibitors. The various modes of inhibition can be compared to the uninhibited reaction.
Specifically, a straight line on a log–log plot containing points (x 0, F 0) and (x 1, F 1) will have the function: = (/) (/), Of course, the inverse is true too: any function of the form = will have a straight line as its log–log graph representation, where the slope of the line is m.
A chemical reaction may undergo different reaction mechanisms at different temperatures. [13] In this case, a Van 't Hoff plot with two or more linear fits may be exploited. Each linear fit has a different slope and intercept, which indicates different changes in enthalpy and entropy for each distinct mechanisms.
A non-vertical line can be defined by its slope m, and its y-intercept y 0 (the y coordinate of its intersection with the y-axis). In this case, its linear equation can be written = +. If, moreover, the line is not horizontal, it can be defined by its slope and its x-intercept x 0. In this case, its equation can be written
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