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The term "azimuthal quantum number" was introduced by Arnold Sommerfeld in 1915 [1]: II:132 as part of an ad hoc description of the energy structure of atomic spectra. . Only later with the quantum model of the atom was it understood that this number, ℓ, arises from quantization of orbital angular moment
In chemistry, this quantum number is very important, since it specifies the shape of an atomic orbital and strongly influences chemical bonds and bond angles. The azimuthal quantum number can also denote the number of angular nodes present in an orbital. For example, for p orbitals, ℓ = 1 and thus the amount of angular nodes in a p orbital is 1.
The classical definition of angular momentum is =.The quantum-mechanical counterparts of these objects share the same relationship: = where r is the quantum position operator, p is the quantum momentum operator, × is cross product, and L is the orbital angular momentum operator.
In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom.So while the word symbol suggests otherwise, it represents an actual value of a physical quantity.
The spin magnetic quantum number m s specifies the z-axis component of the spin angular momentum for a particle having spin quantum number s. For an electron, s is 1 ⁄ 2 , and m s is either + 1 ⁄ 2 or − 1 ⁄ 2 , often called "spin-up" and "spin-down", or α and β.
This notation is used to specify electron configurations and to create the term symbol for the electron states in a multi-electron atom. When writing a term symbol, the above scheme for a single electron's orbital quantum number is applied to the total orbital angular momentum associated to an electron state.
The associated quantum number is the main total angular momentum quantum number j. It can take the following range of values, jumping only in integer steps: [ 1 ] | ℓ − s | ≤ j ≤ ℓ + s {\displaystyle \vert \ell -s\vert \leq j\leq \ell +s} where ℓ is the azimuthal quantum number (parameterizing the orbital angular momentum) and s is ...
Symbol Meaning SI unit of measure ... angular momentum: ... azimuthal quantum number: unitless magnetization: ampere per meter (A/m) moment of force often simply ...