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An enthalpy–entropy chart, also known as the H–S chart or Mollier diagram, plots the total heat against entropy, [1] describing the enthalpy of a thermodynamic system. [2] A typical chart covers a pressure range of 0.01–1000 bar , and temperatures up to 800 degrees Celsius . [ 3 ]
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Description: Blue lines indicate vapor quality, mass percentage in the saturated mixture that is in gas phase . Black lines indicate pressure in pounds per square inch . Grey lines indicate specific volume in square feet per pound-mass of steam
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
As wet steam is heated further, the droplets evaporate, and at a high enough temperature (which depends on the pressure) all of the water evaporates and the system is in vapour–liquid equilibrium. [5] When steam has reached this equilibrium point, it is referred to as saturated steam.
A high-pressure steam locomotive is a steam locomotive with a boiler that operates at pressures well above what would be considered normal for other locomotives. Most locomotives operate with a steam pressure of 200 to 300 psi (1.38 to 2.07 MPa). [1] In the later years of steam, boiler pressures were typically 200 to 250 psi (1.38 to 1.72 MPa).
Superheated steam was widely used in main line steam locomotives. Saturated steam has three main disadvantages in a steam engine: it contains small droplets of water which have to be periodically drained from the cylinders; being precisely at the boiling point of water for the boiler pressure in use, it inevitably condenses to some extent in the steam pipes and cylinders outside the boiler ...
Unless the pressure and temperature reach supercritical levels in the boiler, the temperature range over which the cycle can operate is quite small. As of 2022, most supercritical power plants adopt a steam inlet pressure of 24.1 MPa and inlet temperature between 538°C and 566°C, which results in plant efficiency of 40%.