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II:106 Although Bohr's model would also rely on just the electron to explain the spectrum, he did not assume an electrodynamical model for the atom. The other important advance in the understanding of atomic spectra was the Rydberg–Ritz combination principle which related atomic spectral line frequencies to differences between 'terms ...
The Bohr model worked well for hydrogen and ionized single-electron helium, which impressed Einstein [56] [57] but could not explain more complex elements. By 1919, Bohr was moving away from the idea that electrons orbited the nucleus and developed heuristics to describe them.
The Bohr model posits that electrons revolve around the atomic nucleus in a manner analogous to planets revolving around the Sun. In the simplest version of the Bohr model, the mass of the atomic nucleus is considered to be infinite compared to the mass of the electron, [ 7 ] so that the center of mass of the system, the barycenter , lies at ...
The model's key success lay in explaining the Rydberg formula for the spectral emission lines of atomic hydrogen by using the transitions of electrons between orbits. [24]: 276 While the Rydberg formula had been known experimentally, it did not gain a theoretical underpinning until the Bohr model was introduced. Not only did the Bohr model ...
Calculations based on the Bohr–Sommerfeld model were able to accurately explain a number of more complex atomic spectral effects. For example, up to first-order perturbations, the Bohr model and quantum mechanics make the same predictions for the spectral line splitting in the Stark effect. At higher-order perturbations, however, the Bohr ...
In 1913, Niels Bohr introduced the Bohr model of atomic structure, wherein electrons within atoms can only take on a series of discrete, rather than continuous, energies. This is another example of quantization. The Bohr model successfully explained the discrete nature of atomic spectral lines.
This model, which became known as the Bohr–Sommerfeld model, allowed the orbits of the electron to be ellipses instead of circles, and introduced the concept of quantum degeneracy. The theory would have correctly explained the Zeeman effect, except for the issue of electron spin. Sommerfeld's model was much closer to the modern quantum ...
Complementarity as a physical model derives from Niels Bohr's 1927 presentation in Como, Italy, at a scientific celebration of the work of Alessandro Volta 100 years previous. [4]: 103 Bohr's subject was complementarity, the idea that measurements of quantum events provide complementary information through seemingly contradictory results. [5]