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A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.
In such cases involving strongly dipolar, slowly relaxing solvents, solvation of the transition state does not play a very large role in affecting the reaction rate. Instead, dynamic contributions of the solvent (such as friction, density, internal pressure, or viscosity) play a large role in affecting the reaction rate. [6] [9]
The very pure and finely divided precipitate of calcium carbonate that is generated is a valuable by-product used in the manufacture of toothpaste. The salting-out process used in the manufacture of soaps benefits from the common-ion effect. Soaps are sodium salts of fatty acids. Addition of sodium chloride reduces the solubility of the soap salts.
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
Here, the green substance has a greater solubility in the lower layer than in the upper layer. The partition coefficient, abbreviated P, is defined as a particular ratio of the concentrations of a solute between the two solvents (a biphase of liquid phases), specifically for un-ionized solutes, and the logarithm of the ratio is thus log P.
Class III – low permeability, high solubility . Example: cimetidine; The absorption is limited by the permeation rate but the drug is solvated very fast. If the formulation does not change the permeability or gastro-intestinal duration time, then class I criteria can be applied. Class IV – low permeability, low solubility . Example: bifonazole
Solubility is the property of a gas, liquid or solid substance (the solute) to be held homogeneously dispersed as molecules or ions in a liquid or solid medium (the solvent). In decompression theory, the solubility of gases in liquids is of primary importance, as it is the formation of bubbles from these gases that causes decompression sickness.
The IUPAC definition of a solid solution is a "solid in which components are compatible and form a unique phase". [3]The definition "crystal containing a second constituent which fits into and is distributed in the lattice of the host crystal" given in refs., [4] [5] is not general and, thus, is not recommended.