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1 1 Gibbs free energy: G = ... d f = degree of freedom Average kinetic energy per degree of freedom
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
ΔG equals the maximum amount of non-pV work that can be performed as a result of the chemical reaction for the case of a reversible process. If analysis indicates a positive Δ G for a reaction, then energy — in the form of electrical or other non- pV work — would have to be added to the reacting system for Δ G to be smaller than the non ...
A unit increment of one kelvin is exactly 1.8 times one degree Rankine; thus, to convert a specific temperature on the Kelvin scale to the Rankine scale, x K = 1.8 x °R, and to convert from a temperature on the Rankine scale to the Kelvin scale, x °R = x /1.8 K. Consequently, absolute zero is "0" for both scales, but the melting point of ...
The August–Roche–Magnus formula provides a solution under that approximation: [15] [16] = (+), where is in hPa, and is in degrees Celsius (whereas everywhere else on this page, is an absolute temperature, e.g. in kelvins).
In fractions like "2 nanometers per meter" (2 n m / m = 2 nano = 2×10 −9 = 2 ppb = 2 × 0.000 000 001), so the quotients are pure-number coefficients with positive values less than or equal to 1. When parts-per notations, including the percent symbol (%), are used in regular prose (as opposed to mathematical expressions), they are still pure ...