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Samarium (II) iodide is a one-electron reductant, and typically effects reduction through a series of electron transfer and proton transfer (from protic solvent) steps. [ 4 ][ 3 ] Reducible functional groups include: α-Functionalized carbonyl compounds. Ketones and aldehydes. Carboxylic acids (under strongly acidic or basic conditions) Organic ...
Samarium (II) iodide is an inorganic compound with the formula SmI 2. When employed as a solution for organic synthesis, it is known as Kagan 's reagent. SmI 2 is a green solid and forms a dark blue solution in THF. [1] It is a strong one-electron reducing agent that is used in organic synthesis.
Desulfonylation reactionsare chemical reactions leading to the removal of a sulfonylgroup from organic compounds. As the sulfonyl functional group is electron-withdrawing,[1]methods for cleaving the sulfur–carbon bonds of sulfones are typically reductive in nature. Olefination or replacement with hydrogenmay be accomplished using reductive ...
Alkenes can be made from alcohols by dehydration. This conversion, among others, is used in converting biomass to liquid fuels. [2] The conversion of ethanol to ethylene is a fundamental example: [3] [4] CH 3 CH 2 OH → H 2 C=CH 2 + H 2 O. The reaction is accelerated by acid catalysts such as sulfuric acid and certain zeolites.
Reaction stoichiometry describes the 2:1:2 ratio of hydrogen, oxygen, and water molecules in the above equation. The molar ratio allows for conversion between moles of one substance and moles of another. For example, in the reaction 2 CH 3 OH + 3 O 2 → 2 CO 2 + 4 H 2 O. the amount of water that will be produced by the combustion of 0.27 moles ...
The reduction of nitroaromatics is conducted on an industrial scale. [1] Many methods exist, such as: Catalytic hydrogenation using: Raney nickel [2] or palladium-on-carbon, [3] [4] [5] platinum(IV) oxide, or Urushibara nickel. [6] Iron in acidic media. [7] [8] [9] Sodium hydrosulfite [10] Sodium sulfide (or hydrogen sulfide and base ...
In solutions, mass concentration is commonly encountered as the ratio of mass/ [volume solution], or m/v. In water solutions containing relatively small quantities of dissolved solute (as in biology), such figures may be "percentivized" by multiplying by 100 a ratio of grams solute per mL solution. The result is given as "mass/volume percentage".
Displacement (fluid) Measurement of volume by displacement, (a) before and (b) after an object has been submerged. The amount by which the liquid rises in the cylinder (∆V) is equal to the volume of the object. In fluid mechanics, displacement occurs when an object is largely immersed in a fluid, pushing it out of the way and taking its place.