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The Chézy Formula is a semi-empirical resistance equation [1] [2] which estimates mean flow velocity in open channel conduits. [3] The relationship was conceptualized and developed in 1768 by French physicist and engineer Antoine de Chézy (1718–1798) while designing Paris's water canal system.
The Chézy equation is a pioneering formula in the field of fluid mechanics, and was expanded and modified by Irish engineer Robert Manning in 1889 [1] as the Manning formula. The Chézy formula concerns the velocity of water flowing through conduits and is widely celebrated for its use in open channel flow calculations. [ 2 ]
He compared and evaluated seven best known formulae of the time for the flow of water in a channel: Du Buat (1786), Eyelwein (1814), Weisbach (1845), St. Venant (1851), Neville (1860), Darcy and Bazin (1865), and Ganguillet and Kutter (1869). He calculated the velocity obtained from each formula for a given slope and for hydraulic radii varying ...
Churchill equation [24] (1977) is the only equation that can be evaluated for very slow flow (Reynolds number < 1), but the Cheng (2008), [25] and Bellos et al. (2018) [8] equations also return an approximately correct value for friction factor in the laminar flow region (Reynolds number < 2300). All of the others are for transitional and ...
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
The Henderson–Hasselbalch equation can be used to model these equilibria. It is important to maintain this pH of 7.4 to ensure enzymes are able to work optimally. [10] Life threatening Acidosis (a low blood pH resulting in nausea, headaches, and even coma, and convulsions) is due to a lack of functioning of enzymes at a low pH. [10]
For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y-axis and 1 / T on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation
The Charlot equation, named after Gaston Charlot, is used in analytical chemistry to relate the hydrogen ion concentration, and therefore the pH, with the formal analytical concentration of an acid and its conjugate base. It can be used for computing the pH of buffer solutions when the approximations of the Henderson–Hasselbalch equation ...