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Example of saponification reaction of a triglyceride molecule (left) with potassium hydroxide (KOH) yielding glycerol (purple) and salts of fatty acids ().. Saponification value or saponification number (SV or SN) represents the number of milligrams of potassium hydroxide (KOH) or sodium hydroxide (NaOH) required to saponify one gram of fat under the conditions specified.
Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. [ 1 ] [ 2 ] It is an important type of alkaline hydrolysis .
The Reichert value is an indicator of how much volatile fatty acid can be extracted from a particular fat or oil through saponification. It is equal to the number of millilitres of 0.1 normal hydroxide solution necessary for the neutralization of the water-soluble volatile fatty acids distilled and filtered from 5 grams of a given saponified fat.
(The hydroxide solution used in such a titration is typically made from sodium hydroxide, potassium hydroxide, or barium hydroxide.) [1] It is measure of the steam volatile and water insoluble fatty acids, chiefly caprylic, capric and lauric acids, present in oil and fat. The value is named for the chemist who developed it, Eduard Polenske. [2]
Saltwater soap, also called sailors' soap, is a potassium-based soap for use with seawater. Inexpensive common commercial soap will not lather or dissolve in seawater due to high levels of sodium chloride in the water. Similarly, common soap does not work as well as potassium-based soap in hard water where calcium replaces the sodium, making ...
An approximate chemical formula for beeswax is C 15 H 31 COOC 30 H 61. [10] Its main constituents are palmitate , palmitoleate , and oleate esters of long-chain (30–32 carbons) aliphatic alcohols , with the ratio of triacontanyl palmitate CH 3 (CH 2 ) 29 O-CO-(CH 2 ) 14 CH 3 to cerotic acid CH 3 (CH 2 ) 24 COOH, the two principal constituents ...
A saponifiable lipid is part of the ester functional group. They are made up of long chain carboxylic (of fatty) acids connected to an alcoholic functional group through the ester linkage which can undergo a saponification reaction.
Because it avoids the need to handle lye, a hazardous and very caustic chemical, it is a hobby even children can enjoy under adult supervision. Unlike cold-processed soap, which requires a period of "curing" to allow saponification to complete and excess water to evaporate, the "melt and pour" process is completed once the base has cooled and ...