Search results
Results from the WOW.Com Content Network
Permanganic acid (or manganic(VII) acid) is the inorganic compound with the formula H MnO 4 and various hydrates. [3] This strong oxoacid has been isolated as its dihydrate. It is the conjugate acid of permanganate salts. It is the subject of few publications and its characterization as well as its uses are very limited.
A permanganate can oxidize an amine to a nitro compound, [7] [8] an alcohol to a ketone, [9] an aldehyde to a carboxylic acid, [10] [11] a terminal alkene to a carboxylic acid, [12] oxalic acid to carbon dioxide, [13] and an alkene to a diol. [14] This list is not exhaustive. In alkene oxidations one intermediate is a cyclic Mn(V) species: [15]
Permanganic acid can be prepared by the reaction of dilute sulfuric acid with a solution barium permanganate, the insoluble barium sulfate byproduct being removed by filtering: [3] Ba(MnO 4) 2 + H 2 SO 4 → 2 HMnO 4 + BaSO 4. The sulfuric acid used must be dilute; reactions of permanganates with concentrated sulfuric acid yield the anhydride ...
The purplish-black color of solid potassium permanganate, and the intensely pink to purple color of its solutions, is caused by its permanganate anion, which gets its color from a strong charge-transfer absorption band caused by excitation of electrons from oxo ligand orbitals to empty orbitals of the manganese(VII) center.
The reaction initially produces permanganic acid, HMnO 4 (structurally, HOMnO 3), which is dehydrated by cold sulfuric acid to form its anhydride, Mn 2 O 7: 2 KMnO 4 + 2 H 2 SO 4 → Mn 2 O 7 + H 2 O + 2 KHSO 4. Mn 2 O 7 can react further with sulfuric acid to give the remarkable manganyl(VII) cation MnO + 3, which is isoelectronic with CrO 3:
A ton container is a steel, cylindrical barrel equivalent in length and diameter to two stacked 55-gallon drums. A ton container weighs approximately 1,600 pounds and measures nearly seven feet in length. [1] The United States Army has used ton containers to store and ship bulk chemicals, including chemical agent, since the 1930s.
A rainwater catchment or collection (also known as "rainwater harvesting") system can yield 1,000 litres (260 US gal) of water from 1 cm (0.4 in) of rain on a 100 m 2 (1,100 sq ft) roof. Rainwater tanks are installed to make use of rain water for later use, reduce mains water use for economic or environmental reasons, and aid self-sufficiency.
Potassium permanganate, however, does not have FDA approved uses and therefore non medical grade potassium permanganate is sometimes used for medical use. [citation needed] It is available under a number of brand names including Permasol, Koi Med Tricho-Ex, and Kalii permanganas RFF. [21] It is occasionally called "Condy's crystals". [15]