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As ammonium nitrate is a salt, both the cation, NH + 4, and the anion, NO − 3, may take part in chemical reactions. Solid ammonium nitrate decomposes on heating. At temperatures below around 300 °C, the decomposition mainly produces nitrous oxide and water: NH 4 NO 3 → N 2 O + 2 H 2 O. At higher temperatures, the following reaction ...
In organic chemistry, a nitrate ester is an organic functional group with the formula R−ONO 2, where R stands for any organyl group. They are the esters of nitric acid and alcohols . A well-known example is nitroglycerin , which is not a nitro compound, despite its name.
The anion [Ce(NO 3) 6] 2− is generated by dissolving Ce 2 O 3 in hot and concentrated nitric acid (HNO 3). [2] The salt consists of the hexanitratocerate(IV) anion [Ce(NO 3) 6] 2− and a pair of ammonium cations NH + 4. The ammonium ions are not involved in the oxidising reactions of this salt.
2 HNO → N 2 O + H 2 O. The reaction proceeds via dimerization to hyponitrous acid, H 2 N 2 O 2, which subsequently undergoes dehydration. Therefore, HNO is generally prepared in situ as described above. Nitroxyl is very reactive towards nucleophiles, including thiols. The initial adduct rearranges to a sulfinamide: [11] HNO + RSH → RS(O)NH 2
Fertilizers that improve plant growth are made by neutralizing sulfuric acid (H 2 SO 4) or nitric acid (HNO 3) with ammonia gas (NH 3), making ammonium sulfate or ammonium nitrate. These are salts utilized in the fertilizer.
ammonium perchlorate, ammonium nitrate, and ammonium bicarbonate; Cisplatin ([Pt(NH 3) 2 Cl 2) is a widely used anticancer drug. Ammonia is a ligand forming metal ammine complexes. For historical reasons, ammonia is named ammine in the nomenclature of coordination compounds. One notable ammine complex is cisplatin (Pt(NH 3) 2 Cl 2, a widely ...
ammonium nitrate +25.69 ammonia-30.50 potassium hydroxide-57.61 caesium hydroxide-71.55 sodium chloride +3.87 potassium chlorate +41.38 acetic acid-1.51 sodium hydroxide-44.50 Change in enthalpy ΔH o in kJ/mol in water at 25°C [2]
The decomposition of ammonium nitrate is also a common laboratory method for preparing the gas. Equivalently, it can be obtained by heating a mixture of sodium nitrate and ammonium sulfate: [53] 2 NaNO 3 + (NH 4) 2 SO 4 → Na 2 SO 4 + 2 N 2 O + 4 H 2 O. Another method involves the reaction of urea, nitric acid and sulfuric acid: [54]