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The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Cross of a Beagle and a Cavalier King Charles Spaniel; first deliberately bred in the 1990s by designer dog breeders in Australia as a companion dog with the aim of reducing the scent-hunting drive common in Beagles. [2] Bernedoodle: The bernedoodle, first introduced in 2003, is a cross between a Bernese Mountain Dog and a Poodle. [3] Cavachon
tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
King Charles Spaniels are often mistaken for Cavalier King Charles Spaniels. There are several significant differences between the two breeds, the principal being the size. [41] While the Cavalier weighs on average between 13 and 18 pounds (5.9 and 8.2 kg), [55] the King Charles is smaller at 8 to 14 pounds (3.6 to 6.4 kg). [52]
Dog rescuers recommend that owners follow the 3-3-3 rule when helping their new dogs adjust to a new home. This 'rule' describes how long it can take for an adopted dog to reach certain levels of ...
Alaskan husky. Crossbreeding has played a key characteristic in the development of sled dogs with various crossbreeds developing to meet the specific needs of the era and geographical region, including the Mackenzie River husky, in which European breeds were crossed with Native American dogs to produce a powerful and hardy freighting dog in the 19th century, and the Alaskan husky, bred ...
Dogs commonly give birth in a whelping box, a simple box or pen provided to the dam to help shelter and contain the puppies. A person who intentionally mates dogs to produce puppies is referred to as a dog breeder. Line breeding is the planned breeding of dogs with their relatives. This is done to strengthen the appearance of specific desired ...
Lurcher is an old English term for a crossbred dog; specifically, the result of mating a sighthound with a dog of another type, typically a working breed.The term was first used with this meaning in 1668; it is considered to be derived from the verb lurch, apparently a variant form of lurk, meaning lurk or steal.
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