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The K ATRP value depends on the homo-cleavage energy of the alkyl halide and the redox potential of the Cu catalyst with different ligands. Given two alkyl halides (R 1-X and R 2-X) and two ligands (L 1 and L 2), there will be four combinations between different alkyl halides and ligands. Let K ij ATRP refer to the K ATRP value for R i-X and L ...
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There is a mode of polymerization referred to as reversible-deactivation polymerization which is distinct from living polymerization, despite some common features. Living polymerization requires a complete absence of termination reactions, whereas reversible-deactivation polymerization may contain a similar fraction of termination as conventional polymerization with the same concentration of ...
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ATRP involves the chain initiation of free radical polymerization by a halogenated organic species in the presence of a metal halide. The metal has a number of different oxidation states that allows it to abstract a halide from the organohalide, creating a radical that then starts free radical polymerization.
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Taking star polymers as an example, RAFT differs from other forms of living radical polymerization techniques in that either the R- or Z-group may form the core of the star (See Figure 10). While utilizing the R-group as the core results in similar structures found using ATRP or NMP, the ability to use the Z-group as the core makes RAFT unique.