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A binary resonance ratio in this article should be interpreted as the ratio of number of orbits completed in the same time interval, rather than as the ratio of orbital periods, which would be the inverse ratio. Thus, the 2:3 ratio above means that Pluto completes two orbits in the time it takes Neptune to complete three.
Founded on a few general principles that govern how orbitals interact, the stereoelectronic effect, along with the steric effect, inductive effect, solvent effect, mesomeric effect, and aromaticity, is an important type of explanation for observed patterns of selectivity, reactivity, and stability in organic chemistry. In spite of the ...
Similar to the electron spin resonance (ESR) in which electrons can be excited with an electromagnetic wave with the energy given by the Zeeman effect, in EDSR the resonance can be achieved if the frequency is related to the energy band splitting given by the spin–orbit coupling in solids. While in ESR the coupling is obtained via the ...
In organic chemistry, hyperconjugation (σ-conjugation or no-bond resonance) refers to the delocalization of electrons with the participation of bonds of primarily σ-character. Usually, hyperconjugation involves the interaction of the electrons in a sigma (σ) orbital (e.g. C–H or C–C) with an adjacent unpopulated non-bonding p or ...
It also termed an effect, oscillations, cycles, or resonance. This effect causes the orbit's argument of pericenter to oscillate about a constant value, which in turn leads to a periodic exchange between its eccentricity and inclination. The process occurs on timescales much longer than the orbital periods.
This is a weighted sum of the wavefunctions. Now choose a second hybrid orbital s + √ λ j p j, where p j is directed in some way and λ j is the amount of p character in this second orbital. The value of λ j and direction of p j must be determined so that the resulting orbital can be normalized and so that it is orthogonal to the first ...
In chemistry, a molecular orbital (/ ɒr b ə d l /) is a mathematical function describing the location and wave-like behavior of an electron in a molecule. This function can be used to calculate chemical and physical properties such as the probability of finding an electron in any specific region.
In chemistry, the mesomeric effect (or resonance effect) is a property of substituents or functional groups in a chemical compound. It is defined as the polarity produced in the molecule by the interaction of two pi bonds or between a pi bond and lone pair of electrons present on an adjacent atom. [ 1 ]