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Thermodynamic modelling is a set of different strategies that are used by engineers and scientists to develop models capable of evaluating different thermodynamic properties of a system.
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.
A thermodynamic cycle consists of linked sequences of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. [1]
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The values are organized in a format that makes them readable by a thermodynamic calculation program or for use in a spreadsheet. For example, the Excel-based thermodynamic database FREED creates the following type of datafile, here for a standard pressure of 1 atm. Thermodynamic datafile for MgCl 2 (c,l,g) from FREED. Some values have ...
Hence, all cubic equations of state can be considered 'modified van der Waals equation of state'. There is a very large number of such cubic equations of state. For process engineering, cubic equations of state are today still highly relevant, e.g. the Peng Robinson equation of state or the Soave Redlich Kwong equation of state.