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Lime softening (also known as lime buttering, lime-soda treatment, or Clark's process) [1] is a type of water treatment used for water softening, which uses the addition of limewater (calcium hydroxide) to remove hardness (deposits of calcium and magnesium salts) by precipitation.
In industrial scale water softening plants, the effluent flow from the re-generation process can precipitate scale that can interfere with sewage systems. [3] The slippery feeling associated with washing in soft water is caused by the weaker attraction of the soap to the water ions when the water has been stripped of its mineral content.
A precursor to the soda pulping process was the paper making process developed by Matthias Koops in 1801 which involved washing wood shavings in limewater, adding soda crystals and then boiling the mixture. [2] Soda pulping was one of the first chemical pulping methods and was invented in 1851 by Burgess (United States) and Watts (England).
A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is: CaCO 3 + heat → CaO + CO 2
Calcined gypsum is an alternative material in industrial plasters and mortars. Cement, cement kiln dust, fly ash, and lime kiln dust are potential substitutes for some construction uses of lime. Magnesium hydroxide is a substitute for lime in pH control, and magnesium oxide is a substitute for dolomitic lime as a flux in steelmaking. [28]
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In high pressure boilers, sodium carbonate is used in softening of water by lime soda process, due to this some sodium carbonate maybe left behind in the water. As the concentration of sodium carbonate increases, it undergoes hydrolysis to form sodium hydroxide .
The ammonia-soda process was first patented on 30 June 1838 by Harrison Gray Dyar and John Hemming, [3] [4] who carried it out on an experimental scale in Whitechapel. Many attempts were soon after made in the same direction, both in England and on the continent of Europe, the most remarkable of which was the ingenious combination of apparatus ...