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It consists of calcium cations (Ca 2+) and chloride (Cl −) and hydroxide (− OH) anions. A white solid, it forms by the reaction of hydrogen chloride with calcium hydroxide [3] According to X-ray crystallography, it adopts a layered structure related to brucite (magnesium hydroxide, Mg(OH) 2). [4]
Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction: Ca(OH) 2 → Ca 2+ + 2 OH −. The solubility is affected by the common-ion effect. Its solubility drastically decreases upon addition of hydroxide or calcium sources.
The one-step reaction is shown below: [3] 2 Cl 2 + 2 Ca(OH) 2 → CaCl 2 + Ca(OCl) 2 + 2 H 2 O. Industrial setups allow for the reaction to be conducted in stages to give various compositions, each producing different ratios of calcium hypochlorite, unconverted lime, and calcium chloride. [3]
A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by an atom or group. [1] [2] [3] It can be represented generically as: + +
When dissolved in water, calcium chloride can undergo hydrolysis, especially over time, which can lead to the formation of small amounts of hydrochloric acid and calcium hydroxide: Ca + 2 +2 H 2 O ⇌ Ca(OH) 2 +2 H +. This reaction can lower the pH of the solution, making it more acidic. [68] Acidic solutions may harm plant tissues and disrupt ...
Pozzolanic reaction is a long term reaction, which involves dissolved silicic acid, water and CaO or Ca(OH) 2 or other pozzolans to form a strong cementation matrix. This process is often irreversible. Sufficient amount of free calcium ion and a high pH of 12 and above is needed to initiate and maintain the pozzolanic reaction. [2]
Ba(OH) 2 + 2 H + → Ba 2+ + 2 H 2 O. The same equation relating the concentrations of acid and base applies. The concept of neutralization is not limited to reactions in solution. For example, the reaction of limestone with acid such as sulfuric acid is also a neutralization reaction. [Ca,Mg]CO 3 (s) + H 2 SO 4 (aq) → (Ca 2+, Mg 2+)(aq) + SO ...
Hydrogen peroxide (H 2 O 2) can be used as HOCl scavenger whose byproducts do not interfere in the Pinnick oxidation reaction: HOCl + H 2 O 2 → HCl + O 2 + H 2 O. In a weakly acidic condition, fairly concentrated (35%) H 2 O 2 solution undergoes a rapid oxidative reaction with no competitive reduction reaction of HClO 2 to form HOCl. HClO 2 ...