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The Levich equation is written as: = where I L is the Levich current (A), n is the number of moles of electrons transferred in the half reaction (number), F is the Faraday constant (C/mol), A is the electrode area (cm 2), D is the diffusion coefficient (see Fick's law of diffusion) (cm 2 /s), ω is the angular rotation rate of the electrode (rad/s), ν is the kinematic viscosity (cm 2 /s), C ...
An RDE cannot be used to observe the behavior of the electrode reaction products, since they are continually swept away from the electrode. However, the rotating ring-disk electrode is well suited to investigate this further reactivity. The peak current in a cyclic voltammogram for an RDE is a plateau like region, governed by the Levich ...
The Koutecký–Levich equation models the measured electric current at an electrode from an electrochemical reaction in relation to the kinetic activity and the mass transport of reactants. A visualization of the Koutecký–Levich equation. The graph shows the measured current as a function of the mass transport current for given kinetic current.
The RRDE setup allows for many additional experiments well beyond the capacity of a RDE. For example, while one electrode conducts linear sweep voltammetry the other can be kept at a constant potential or also swept in a controlled manner. Step experiments with each electrode acting independently can be conducted.
A Levich constant (B) is often used in order to simplify the Levich equation. [1] Furthermore, B is readily extracted from rotating disk electrode experimental data. The B can be defined as: [ 2 ]
Thus the reorganization energy for chemical redox reactions, which is a Gibbs free energy, is also a parabolic function of Δe of this hypothetical transfer, For the self exchange reaction, where for symmetry reasons Δe = 0.5, the Gibbs free energy of activation is ΔG(0) ‡ = λ o /4 (see Fig. 1 and Fig. 2 intersection of the parabolas I and ...
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