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Ion-exchange resin beads. An ion-exchange resin or ion-exchange polymer is a resin or polymer that acts as a medium for ion exchange, that is also known as an ionex. [1] It is an insoluble matrix (or support structure) normally in the form of small (0.25–1.43 mm radius) microbeads, usually white or yellowish, fabricated from an organic polymer substrate.
Idealized image of cation-exchange resin performing water softening. It shows sodium ions being released by the resin, and replaced with calcium ions captured from water. Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water.
In the case of a water softener, the cation exchange resin is exchanging sodium (the Na + ion of NaCl) for hardness minerals such as calcium and magnesium. A dealkalizer contains strong base anion exchange resin that exchanges chloride (the Cl – ion of the NaCl) for carbonate (CO − 3), bicarbonate (H C O − 3) and sulfate (SO 2− 4). As ...
Water softeners are usually regenerated with brine containing 10% sodium chloride. [7] Aside from the soluble chloride salts of divalent cations removed from the softened water, softener regeneration wastewater contains the unused 50–70% of the sodium chloride regeneration flushing brine required to reverse ion-exchange resin equilibria.
Water softening is achieved by percolating hard water through a bed of the sodium form of cross-linked polystyrene sulfonate. The hard ions such as calcium (Ca 2+) and magnesium (Mg 2+) adhere to the sulfonate groups, displacing sodium ions. The resulting solution of sodium ions is softened.
Ion-exchange resins are polymers with a net negative or positive charge. Cation-exchange resins consist of an anionic polymer with countercations, typically Na + (sodium). The resin has a higher affinity for highly charged countercations, for example by Ca 2+ (calcium) in the case of water softening.
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