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The following is a list of straight-chain alkanes, the total number of isomers of each (including branched chains), and their common names, sorted by number of carbon atoms. [ 1 ] [ 2 ] Number of C atoms
Number and name the side chains before the name of the root chain; If there are multiple side chains of the same type, use prefixes such as "di-" and "tri-" to indicate it as such, and number each one. Add side chain names in alphabetical (disregarding "di-" etc. prefixes) order in front of the name of the root chain
Hydrocarbons with the same molecular formula but different structural formulae are called structural isomers. [1]: 625 As given in the example of 3-methylhexane and its higher homologues, branched hydrocarbons can be chiral. [1]: 627 Chiral saturated hydrocarbons constitute the side chains of biomolecules such as chlorophyll and tocopherol. [3]
The group may be represented as −CH 2 − or >CH 2, where the '>' denotes the two bonds. This stands in contrast to a situation where the carbon atom is bound to the rest of the molecule by a double bond, which is preferably called a methylidene group, represented =CH 2. [2] Formerly the methylene name was used for both isomers.
The side chain is a hydrocarbon branching element of a molecule that is attached to a larger hydrocarbon backbone. It is one factor in determining a molecule's properties and reactivity. [2] A side chain is also known as a pendant chain, but a pendant group (side group) has a different definition.
For example, the carbon frame of norbornane contains a total of 7 atoms, hence the root name heptane. This molecule has two paths of 2 carbon atoms and a third path of 1 carbon atom between the two bridgehead carbons, so the brackets are filled in descending order: [2.2.1]. Addition of the prefix bicyclo gives the total name bicyclo[2.2.1]heptane.
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In chemistry, an open-chain compound (or open chain compound) or acyclic compound (Greek prefix α 'without' and κύκλος 'cycle') is a compound with a linear structure, rather than a cyclic one. [1] An open-chain compound having no side groups is called a straight-chain compound (also spelled as straight chain compound).