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Drawn semi-crystalline polymers are the strongest polymeric materials due to the stress-induced ordering of the molecular chains. [27] Other defects, such as voids, occur in the semi-crystalline polymer under tensile stress and can drive the formation of the neck. The voids can be observed via small angle x-ray scattering.
By varying the monomer ratios and method by which the monomers are combined different forms of EPM can be formed (with a wide range of Mooney viscosities); ranging from amorphous to semi-crystalline. A third, non-conjugated diene monomer can be terpolymerized in a controlled manner to maintain an unsaturated backbone ready for vulcanization or ...
Many plastics are completely amorphous (without a highly ordered molecular structure), [22] including thermosets, polystyrene, and methyl methacrylate (PMMA). Crystalline plastics exhibit a pattern of more regularly spaced atoms, such as high-density polyethylene (HDPE), polybutylene terephthalate (PBT), and polyether ether ketone (PEEK ...
Amorphous solids are the opposite of crystalline. The atoms or molecules in amorphous substances are arranged randomly without any long-range order. As a result, they do not have a sharp melting point. The phase transition from solid to liquid occurs over a range of temperatures. [citation needed] Some examples include glass, rubber and some ...
Amorphous and semi-amorphous plastics are less resistant to chemical attack and environmental stress cracking because they lack a crystalline structure. Brittleness can be decreased with the addition of plasticizers , which increases the mobility of amorphous chain segments to effectively lower the glass transition temperature.
In polymer physics, spherulites (from Greek sphaira = ball and lithos = stone) are spherical semicrystalline regions inside non-branched linear polymers. Their formation is associated with crystallization of polymers from the melt and is controlled by several parameters such as the number of nucleation sites, structure of the polymer molecules, cooling rate, etc. Depending on those parameters ...
Amorphous materials, such as liquids and glasses, represent an intermediate case, having order over short distances (a few atomic or molecular spacings) but not over longer distances. Many materials, such as glass-ceramics and some polymers, can be prepared in such a way as to produce a mixture of crystalline and amorphous regions. In such ...
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is characteristic of a crystal. The terms " glass " and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo ...