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  2. Restriction (mathematics) - Wikipedia

    en.wikipedia.org/wiki/Restriction_(mathematics)

    For a function to have an inverse, it must be one-to-one.If a function is not one-to-one, it may be possible to define a partial inverse of by restricting the domain. For example, the function = defined on the whole of is not one-to-one since = for any .

  3. Crystallographic restriction theorem - Wikipedia

    en.wikipedia.org/wiki/Crystallographic...

    The crystallographic restriction theorem in its basic form was based on the observation that the rotational symmetries of a crystal are usually limited to 2-fold, 3-fold, 4-fold, and 6-fold. However, quasicrystals can occur with other diffraction pattern symmetries, such as 5-fold; these were not discovered until 1982 by Dan Shechtman .

  4. Corestriction - Wikipedia

    en.wikipedia.org/wiki/Corestriction

    In mathematics, a corestriction [1] of a function is a notion analogous to the notion of a restriction of a function. The duality prefix co- here denotes that while the restriction changes the domain to a subset, the corestriction changes the codomain to a subset. However, the notions are not categorically dual.

  5. Crossover experiment (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Crossover_experiment...

    Crossover experiments allow for experimental study of a reaction mechanism. Mechanistic studies are of interest to theoretical and experimental chemists for a variety of reasons including prediction of stereochemical outcomes, optimization of reaction conditions for rate and selectivity, and design of improved catalysts for better turnover number, robustness, etc. [6] [7] Since a mechanism ...

  6. Reaction–diffusion system - Wikipedia

    en.wikipedia.org/wiki/Reaction–diffusion_system

    Reaction–diffusion systems are naturally applied in chemistry. However, the system can also describe dynamical processes of non-chemical nature. Examples are found in biology, geology and physics (neutron diffusion theory) and ecology. Mathematically, reaction–diffusion systems take the form of semi-linear parabolic partial differential ...

  7. Job plot - Wikipedia

    en.wikipedia.org/wiki/Job_plot

    Within chemistry, a Job plot, otherwise known as the method of continuous variation or Job's method, is a method used in analytical chemistry to determine the stoichiometry of a binding event. The method is named after Paul Job and is also used in instrumental analysis and advanced chemical equilibrium texts and research articles.

  8. Blumberg theorem - Wikipedia

    en.wikipedia.org/wiki/Blumberg_theorem

    Imagine, for instance, defining a function : by picking each value () completely at random (so its graph would be appear as infinitely many points scattered randomly about the plane ); no matter how you ended up imagining it, the Blumberg theorem guarantees that even this function has some dense subset on which its restriction is continuous.

  9. Energy minimization - Wikipedia

    en.wikipedia.org/wiki/Energy_minimization

    In the field of computational chemistry, energy minimization (also called energy optimization, geometry minimization, or geometry optimization) is the process of finding an arrangement in space of a collection of atoms where, according to some computational model of chemical bonding, the net inter-atomic force on each atom is acceptably close to zero and the position on the potential energy ...