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Polarizability is responsible for a material's dielectric constant and, at high (optical) frequencies, its refractive index. The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. [1]
The refractive index of materials varies with the wavelength (and frequency) of light. [27] This is called dispersion and causes prisms and rainbows to divide white light into its constituent spectral colors. [28] As the refractive index varies with wavelength, so will the refraction angle as light goes from one material to another.
The Lorentz–Lorenz equation is similar to the Clausius–Mossotti relation, except that it relates the refractive index (rather than the dielectric constant) of a substance to its polarizability. The Lorentz–Lorenz equation is named after the Danish mathematician and scientist Ludvig Lorenz , who published it in 1869, and the Dutch ...
Refraction at interface. Many materials have a well-characterized refractive index, but these indices often depend strongly upon the frequency of light, causing optical dispersion. Standard refractive index measurements are taken at the "yellow doublet" sodium D line, with a wavelength (λ) of 589 nanometers.
Molar refractivity, [1] [2], is a measure of the total polarizability of a mole of a substance. For a perfect dielectric which is made of one type of molecule, the molar refractivity is proportional to the polarizability of a single molecule of the substance. For real materials, intermolecular interactions (the effect of the induced dipole ...
In a birefringent material, a wave consists of two polarization components which generally are governed by different effective refractive indices. The so-called slow ray is the component for which the material has the higher effective refractive index (slower phase velocity), while the fast ray is the one with a lower effective refractive index ...
A typical polymer has a refractive index of 1.30–1.70, but a higher refractive index is often required for specific applications. The refractive index is related to the molar refractivity, structure and weight of the monomer. In general, high molar refractivity and low molar volumes increase the refractive index of the polymer. [1]
The phase velocity of light in a medium is commonly expressed using the index of refraction n, defined as the speed of light (in free space) divided by its speed in the medium. The difference in the refractive indices between the two circular polarizations quantifies the strength of the circular birefringence (polarization rotation),