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195.4 K (−77.75 °C), 6.060 kPa: Critical point: 405.5 K (132.3 °C), 11.300 MPa: Std enthalpy change of fusion, Δ fus H o +5.653 kJ/mol Std entropy change of fusion, Δ fus S o +28.93 J/(mol·K) Std enthalpy change of vaporization, Δ vap H o +23.35 kJ/mol at BP of −33.4 °C Std entropy change of vaporization, Δ vap S o +97.41 J/(mol·K ...
One structure is trigonal bipyramidal molecular geometry type NH 5 molecule. Its nitrogen atom and hydrogen atoms are covalently bounded, and its symmetry group is D 3h. [1] Another predicted structure of nitrogen pentahydride is an ionic compound, composed of an ammonium ion and a hydride ion (NH 4 + H −). Until now, no one has synthesized ...
In a crystal structure the coordination geometry of an atom is the geometrical pattern of coordinating atoms where the definition of coordinating atoms depends on the bonding model used. [1] For example, in the rock salt ionic structure each sodium atom has six near neighbour chloride ions in an octahedral geometry and each chloride has ...
Ammonium bifluoride, as its name indicates, contains an ammonium cation ([NH 4] +), and a bifluoride (or hydrogen difluoride) anion ([HF 2] −).The triatomic bifluoride anion features a strong three-center four-electron bond (specifically, a symmetrical hydrogen bond) with a bond energy greater than 155 kJ/mol, [2] and an H-F length of 114 pm. [3]
The chromium atom is surrounded by six nitrogen atoms in an octahedral geometry. The NH 3 ligands are mutually trans and the Cr–NCS groups are linear. The salt crystallizes with one molecule of water. [1] It was first reported in 1863. [3]
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged molecular ion with the chemical formula NH + 4 or [NH 4] +.It is formed by the addition of a proton (a hydrogen nucleus) to ammonia (NH 3).
Ammonium oxalate is a chemical compound with the chemical formula [N H 4] 2 C 2 O 4.Its formula is often written as (NH 4) 2 C 2 O 4 or (COONH 4) 2.It is an ammonium salt of oxalic acid.It consists of ammonium cations ([NH 4] +) and oxalate anions (C 2 O 2− 4).
The structure of this salt was verified by X-ray crystallography. The respective C–O and C–N distances are 1.174(8) and 1.192(7) Å , consistent with the O=C=N − description. Ammonium cation [NH 4 ] + forms hydrogen bonds with cyanate anion O=C=N − , but to N, not to O. [ 1 ]